2023 Articles

Improvements in the determination of attogram-sized ²³¹Pa in dissolved and particulate fractions of seawater via multi-collector inductively coupled plasma mass spectrometry

Zhang, Pu; Lu, Yanbin; Zhang, Zhe; Edwards, Richard L.; Anderson, Robert F.; Lam, Phoebe

A technique is developed to quantify the ultra-trace ²³¹Pa (35–3904 ag) concentration in seawater using multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). The method is a modification of the process developed by Shen et al. (Anal Chem 75(5):1075–1079, 2003. https://doi.org/10.1021/ac026247r) and extends it to the application of very low levels of actinides, and the 35 ag 231Pa can be measured with a precision of 15%. The total process blank for the water column was 0.02 ag/g, while the values of the large and small particles were ~ 30 ag/g. The ionization efficiency (ions generated/atom loaded) varies from 0.7 to 2.4%. The measurement time is 2–5 min. The amount of ²³¹Pa needed to produce ²³¹Pa data with an uncertainty of  ± 0.8–15% is 35–3904 ag (~ 0.9 × 105 to 10 × 10⁶ atoms).

Replicate measurements of known standards and seawater samples demonstrate that the analytical precision approximates that expected from counting statistics, and that based on detection limits of 52 ag, 55 ag, and 28 ag, protactinium can be detected in a minimum seawater sample size of ~ 2.6 L for small suspended particulate matter (> 0.8 μm and < 51 μm), ~ 3.0 L for large suspended particulate matter (> 51 μm), and ~ 56 mL for filtered (< 0.45 μm) seawater. The concentration of 231Pa (several attograms per liter) can be determined with an uncertainty of  ± 2–8% (2𝜎) for suspended particulate matter filtered from ~ 60 L of seawater. For the dissolved fraction, ~ 1 L of seawater yields ²³¹Pa measurements with a precision of 0.8–10%. The sample size requirements are several orders of magnitude less than traditional decay-counting techniques, and the precision is better than that previously reported for ICP-MS techniques. Our technique can also be applied to other environmental samples, including river, lake, and cave water samples.