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Molecular Cloud Chemistry and The Importance of Dielectronic Recombination

Bryans, P.; Kreckel, H.; Roueff, E.; Wakelam, V.; Savin, Daniel Wolf

Dielectronic recombination (DR) of singly charged ions is a reaction pathway that is commonly neglected in chemical models of molecular clouds. In this study we include state-of-the-art DR data for He+, C+, N+, O+, Na+, and Mg+ in chemical models used to simulate dense molecular clouds, protostars, and diffuse molecular clouds. We also update the radiative recombination (RR) rate coefficients for H+, He+, C+, N+, O+, Na+, and Mg+ to the current state-of-the-art values. The new RR data have little effect on the models. However, the inclusion of DR results in significant differences in gas-grain models of dense, cold molecular clouds for the evolution of a number of surface and gas-phase species. We find differences of a factor of 2 in the abundance for 74 of the 655 species at times of 104-106 yr in this model when we include DR. Of these 74 species, 16 have at least a factor of 10 difference in abundance. We find the largest differences for species formed on the surface of dust grains. These differences are due primarily to the addition of C+ DR, which increases the neutral C abundance, thereby enhancing the accretion of C onto dust. These results may be important for the warm-up phase of molecular clouds when surface species are desorbed into the gas phase. We also note that no reliable state-of-the-art RR or DR data exist for Si+, P+, S+, Cl+, and Fe+. Modern calculations for these ions are needed to better constrain molecular cloud models.


Also Published In

The Astrophysical Journal

More About This Work

Academic Units
Astronomy and Astrophysics
Published Here
March 20, 2013