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Volume-wise destruction of the antiferromagnetic Mott insulating state through quantum tuning

Frandsen, Benjamin A.; Liu, Lian; Cheung, Sky Chance; Khasanov, Rustem; Guguchia, Zurab; Morenzoni, Elvezio; Munsie, Timothy J. S.; Hallas, Alannah M.; Cai, Yipeng; Wilson, Murray N.; Luke, Graeme M.; Chen, Bijuan; Li, Wenmin; Ding, Cui; Jin, Changqing; Guo, Shengli; Ning, Fanlong; Ito, Takashi U.; Higemoto, Wataru; Billinge, Simon J. L.; Sakamoto, Shoya; Fujimori, Atsushi; Murakami, Taito; Kageyama, Hiroshi; Alonso, Jose Antonio; Kotliar, Gabriel; Imada, Masatoshi; Uemura, Yasutomo J.

RENiO3 (RE=rare-earth element) and V2O3 are archetypal Mott insulator systems. When tuned by chemical substitution (RENiO3) or pressure (V2O3), they exhibit a quantum phase transition (QPT) between an antiferromagnetic Mott insulating state and a paramagnetic metallic state. Because novel physics often appears near a Mott QPT, the details of this transition, such as whether it is first or second order, are important. Here, we demonstrate through muon spin relaxation/rotation (μSR) experiments that the QPT in RENiO3 and V2O3 is first order: the magnetically ordered volume fraction decreases to zero at the QPT, resulting in a broad region of intrinsic phase separation, while the ordered magnetic moment retains its full value until it is suddenly destroyed at the QPT. These findings bring to light a surprising universality of the pressure-driven Mott transition, revealing the importance of phase separation and calling for further investigation into the nature of quantum fluctuations underlying the transition.


Also Published In

Nature Communications

More About This Work

Academic Units
Applied Physics and Applied Mathematics
Published Here
October 21, 2016