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Stereoselective E/Z photoisomerization of oxazolidinone functionalized enecarbamates: direct and triplet sensitized irradiation

Saito, Hideaki; Sivaguru, Jayaraman; Jockusch, Steffen; Inoue, Yoshihisa; Adam, Waldemar; Turro, Nicholas J.

Oxazolidinone-functionalized enecarbamates undergo diastereoselective E/Z photoisomerization upon direct and triplet sensitized irradiations with chiral/achiral sensitizers, showing that the enhanced product diastereoselectivity depends on the solvent and temperature.

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Title
Chemical Communications
DOI
https://doi.org/10.1039/b504413h

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Academic Units
Chemistry
Published Here
July 19, 2010