Academic Commons

Articles

Photochemistry of ketones adsorbed on size/shape selective zeolites. A supramolecular approach to persistent carbon centered radicals

Turro, Nicholas J.; McDermott, Ann E.; Lei, Xuegong; Li, Wei; Abrams, Lloyd; Ottavianai, M. Francesca; Beard, Hege Støgård; Houk, Kendall N.; Beno, Brett R.; Lee, Patrick S.

2H NMR, EPR, computational and product analyses of the photolysis of 2,4-diphenylpentan-3-one (DPP) adsorbed on MFI size/shape selective zeolites are consistent with supramolecular structural changes as a function of surface coverage that provide a novel method for the generation of persistent diffusing organic free radicals.

Files

Also Published In

Title
Chemical Communications
DOI
https://doi.org/10.1039/a708691a

More About This Work

Academic Units
Chemistry
Published Here
July 26, 2010