2025 Articles

Dissociative electron recombination and rotational cooling of the deuterated triatomic hydrogen ions H₂D⁺ and D₂H⁺ ions

Znotins, A.; Faure, A.; Greene, C. H.; Grieser, Manfred; Grussie, F.; Isberner, Leonard W.; Kálosi, Ábel; Kokoouline, V.; Müll, Damian; Paul, Daniel; Pezzella, M.; Savin, Daniel Wolf; Schippers, Stefan; Tennyson, Jonathan; Wolf, Andreas; Novotný, Oldřich; Kreckel, Holger

We have measured the dissociative recombination (DR) of the deuterated triatomic hydrogen ions H₂D⁺ and D₂H⁺ as a function of storage time at the Cryogenic Storage Ring (CSR). Both molecular ions were stored for up to 1000 s inside the cryogenic vacuum of the CSR prior to the electron recombination measurements, allowing them to cool to their lowest rotational states. We implement a comprehensive model for all relevant processes to predict the internal state evolution of the ions during storage inside the CSR, employing calculated radiative transition strengths and state-selective rate coefficients for electron collisions. Our DR rate coefficient measurements with deuterated triatomic hydrogen ions in defined quantum states allow for meaningful comparisons with state-of-the-art theoretical calculations, paving the way for a better understanding of the complex DR process for polyatomic molecular ions.