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High efficiency nanocomposite sorbents for CO2 capture based on amine-functionalized mesoporous capsules

Genggeng Qi; Yanbing Wang; Luis Estevez; Xiaonan Duan; Nkechi Anako; Ah-Hyung Park; Wen Li; Christopher W. Jones; Emmanuel P. Giannelis

Title:
High efficiency nanocomposite sorbents for CO2 capture based on amine-functionalized mesoporous capsules
Author(s):
Qi, Genggeng
Wang, Yanbing
Estevez, Luis
Duan, Xiaonan
Anako, Nkechi
Park, Ah-Hyung
Li, Wen
Jones, Christopher W.
Giannelis, Emmanuel P.
Date:
Type:
Articles
Department:
Earth and Environmental Engineering
Volume:
4
Permanent URL:
Book/Journal Title:
Energy & Environmental Science
Abstract:
A novel high efficiency nanocomposite sorbent for CO2 capture has been developed based on oligomeric amine (polyethylenimine, PEI, and tetraethylenepentamine, TEPA) functionalized mesoporous silica capsules. The newly synthesized sorbents exhibit extraordinary capture capacity up to 7.9 mmol g−1 under simulated flue gas conditions (pre-humidified 10% CO2). The CO2 capture kinetics were found to be fast and reached 90% of the total capacities within the first few minutes. The effects of the mesoporous capsule features such as particle size and shell thickness on CO2 capture capacity were investigated. Larger particle size, higher interior void volume and thinner mesoporous shell thickness all improved the CO2 capacity of the sorbents. PEI impregnated sorbents showed good reversibility and stability during cyclic adsorption–regeneration tests (50 cycles).
Subject(s):
Physical chemistry
Publisher DOI:
http://dx.doi.org/10.1039/C0EE00213E
Item views:
114
Metadata:
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