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Photochemistry of ketones adsorbed on size/shape selective zeolites. A supramolecular approach to persistent carbon centered radicals

Nicholas J. Turro; Ann E. McDermott; Xuegong Lei; Wei Li; Lloyd Abrams; M. Francesca Ottavianai; Hege Støgård Beard; Kendall N. Houk; Brett R. Beno; Patrick S. Lee

Title:
Photochemistry of ketones adsorbed on size/shape selective zeolites. A supramolecular approach to persistent carbon centered radicals
Author(s):
Turro, Nicholas J.
McDermott, Ann E.
Lei, Xuegong
Li, Wei
Abrams, Lloyd
Ottavianai, M. Francesca
Beard, Hege Støgård
Houk, Kendall N.
Beno, Brett R.
Lee, Patrick S.
Date:
Type:
Articles
Department:
Chemistry
Volume:
6
Permanent URL:
Book/Journal Title:
Chemical Communications
Abstract:
2H NMR, EPR, computational and product analyses of the photolysis of 2,4-diphenylpentan-3-one (DPP) adsorbed on MFI size/shape selective zeolites are consistent with supramolecular structural changes as a function of surface coverage that provide a novel method for the generation of persistent diffusing organic free radicals.
Subject(s):
Chemistry
Publisher DOI:
http://dx.doi.org/10.1039/a708691a
Item views:
283
Metadata:
text | xml
Suggested Citation:
Nicholas J. Turro, Ann E. McDermott, Xuegong Lei, Wei Li, Lloyd Abrams, M. Francesca Ottavianai, Hege Støgård Beard, Kendall N. Houk, Brett R. Beno, Patrick S. Lee, 1998, Photochemistry of ketones adsorbed on size/shape selective zeolites. A supramolecular approach to persistent carbon centered radicals, Columbia University Academic Commons, http://hdl.handle.net/10022/AC:P:9388.

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