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Photochemistry of ketones adsorbed on size/shape selective zeolites. A supramolecular approach to persistent carbon centered radicals

Nicholas J. Turro; Ann E. McDermott; Xuegong Lei; Wei Li; Lloyd Abrams; M. Francesca Ottavianai; Hege Støgård Beard; Kendall N. Houk; Brett R. Beno; Patrick S. Lee

Title:
Photochemistry of ketones adsorbed on size/shape selective zeolites. A supramolecular approach to persistent carbon centered radicals
Author(s):
Turro, Nicholas J.
McDermott, Ann E.
Lei, Xuegong
Li, Wei
Abrams, Lloyd
Ottavianai, M. Francesca
Beard, Hege Støgård
Houk, Kendall N.
Beno, Brett R.
Lee, Patrick S.
Date:
Type:
Articles
Department:
Chemistry
Volume:
6
Permanent URL:
Book/Journal Title:
Chemical Communications
Abstract:
2H NMR, EPR, computational and product analyses of the photolysis of 2,4-diphenylpentan-3-one (DPP) adsorbed on MFI size/shape selective zeolites are consistent with supramolecular structural changes as a function of surface coverage that provide a novel method for the generation of persistent diffusing organic free radicals.
Subject(s):
Chemistry
Publisher DOI:
http://dx.doi.org/10.1039/a708691a
Item views:
271
Metadata:
text | xml

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