Articles:
Controlled diastereoselectivity at the alkene-geometry through selective encapsulation: E-Z photoisomerization of oxazolidinone-functionalized enecarbamates within hydrophobic nano-cavities
Hideaki Saito; J. Sivaguru; Steffen Jockusch; Joanne Dyer; Yoshihisa Inoue; Waldemar Adam; Nicholas J. Turro
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- Title:
- Controlled diastereoselectivity at the alkene-geometry through selective encapsulation: E-Z photoisomerization of oxazolidinone-functionalized enecarbamates within hydrophobic nano-cavities
- Author(s):
-
Saito, Hideaki
Sivaguru, J.
Jockusch, Steffen
Dyer, Joanne
Inoue, Yoshihisa
Adam, Waldemar
Turro, Nicholas J. - Date:
- 2007
- Type:
- Articles
- Department:
- Chemistry
- Volume:
- 8
- Permanent URL:
- http://hdl.handle.net/10022/AC:P:8600
- Book/Journal Title:
- Chemical Communications
- Abstract:
- Photoisomerization of encapsulated Z-enecarbamates within the hydrophobic chiral cavities of γ-CD showed higher diastereoselectivities in the photoproducts than those obtained in solution. The selective encapsulation of the enecarbamates and the following isomerization process are both diastereoselectively controlled by γ-CD.
- Subject(s):
- Chemistry
- DOI:
- http://dx.doi.org/10.1039/b609177f
- Item views:
- 171