Hideaki Saito; J. Sivaguru; Steffen Jockusch; Joanne Dyer; Yoshihisa Inoue; Waldemar Adam; Nicholas J. Turro
- Controlled diastereoselectivity at the alkene-geometry through selective encapsulation: E-Z photoisomerization of oxazolidinone-functionalized enecarbamates within hydrophobic nano-cavities
Turro, Nicholas J.
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- Chemical Communications
- Photoisomerization of encapsulated Z-enecarbamates within the hydrophobic chiral cavities of Î³-CD showed higher diastereoselectivities in the photoproducts than those obtained in solution. The selective encapsulation of the enecarbamates and the following isomerization process are both diastereoselectively controlled by Î³-CD.
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